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B6db activities: ktmb

Description Acyl-CoA phenylalanine C-2 acyltransferase (decarboxylating) (2.3.1.-)
Catalyzed reaction 2-phenylmethyl-fumaryl-CoA + L-phenylalanine = 2-methylphenyl-4-oxo-5-amino-phenylhex-2-enoate (MOAPEn) + CoA + CO(2).
Cofactor Pyridoxal-phosphate.
An amino acid C-acyltransferase.
The enzyme is involved in the biosynthesis of the carbonylmethylene structure found in the ketomemicin-class pseudotripeptides.
Organisms -Eubacteria


ktmb (0)
Links Enzyme (activities) ktmb
BRENDA (activities) ktmb
KEGG (pathways) ktmb
PLPMDB (PLP mutants) ktmb
 Kawata J, Naoe T, Ogasawara Y, Dairi T (2017) Biosynthesis of the Carbonylmethylene Structure Found in the Ketomemicin Class of Pseudotripeptides Angew Chem Int Ed Engl 56 2026-2029.

Articles on ktmb
last changed 2019/09/17 14:15

B6db activities